The Chemistry of Organocopper CompoundsCopper in organic synthesis has seen a tremendous development over the past ten years. This text represents the most comprehensive survey on the use of Copper and Cuprates in organic synthesis. The first time that the Patai Series touches on Copper compounds, it contains contributions by leading experts, and delivers the quality expected from the Patai Series. |
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Table des matières
| 9 | |
| 18 | |
| 23 | |
Thermochemistry of organocopper compounds | 145 |
NMR of organocopper compounds | 163 |
Photochemical transformations involving copper porphyrins | 217 |
Electrochemistry of organocopper compounds | 247 |
Gasphase chemistry of organocopper compounds | 279 |
Transmetalation reactions producing organocopper compounds | 443 |
Carbocupration of alkynes | 527 |
Oxidation of organocopper compounds | 585 |
Coppermediated asymmetric allylic alkylations | 603 |
Coppercatalyzed enantioselective conjugate addition | 693 |
CopperI hydride reagents and catalysts | 731 |
Silyl and stannyl derivatives of organocopper compounds | 775 |
Coppermediated and coppercatalyzed addition and substitution | 857 |
Jeanine Tortajada | 298 |
Biochemistry of organocopper compounds | 347 |
NFunctionalized organocuprates | 365 |
R Karl Dieter and Rhett T Watson | 406 |
Coppermediated crosscoupling reactions | 881 |
Fluorinated organocopper reagents | 991 |
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Expressions et termes fréquents
acetylene acetylide acid adduct aggregate Alexakis alkenyl alkyl alkynes amines Angew anion aryl asymmetric B. H. Lipshutz bromide carbocupration carbon carbonyl catalytic cations Chem chiral chloride complexes conjugate addition conjugate addition reactions coordination copper atoms copper-catalyzed copper(I corresponding coupling coworkers crystal structure determination Cu(I Cu(II CuCl CuCN cuprate cyclic diastereoselectivity diethyl ether dimeric efficient electron electrophiles enantioselective enolate enones equation equiv esters Et2O ether Figure first formation Grignard reagents halides hydride i-Pr Inorg interaction intermediate iodides ions ketones Knochel Koten Krause leaving group ligand lithium metal methyl Molecular geometry molecules n-Bu Nakamura nucleophilic observed organocopper compounds organocopper reagents organocuprate Organomet Organometallics oxidation Ph Ph Phys presence propargyl reaction reactivity reduction regioselectivity Scheme silyl silylcuprates solid solvent species spectra stannylcuprates stereoselective steric substitution substrates synthesis t-Bu Tetrahedron Lett transmetalation vinyl X-ray crystal structure yields

