On the Catalytic Efficacy of Low-Oxidation State Group 14 ComplexesThis outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal–metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry. |
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Table des matières
| 1 | |
| 13 | |
| 43 | |
4 Reactivity of LowCoordinate Group 14 ElementII Hydride Complexes | 113 |
5 Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrylene Derivatives | 146 |
6 The Use of a Bulky BorylSubstituted Amide Ligand in LowOxidation State Group 14 Element Chemistry | 205 |
General Synthetic Considerations | 238 |
Appendix B Crystallographic Data | 239 |
Computational Studies | 240 |
Autres éditions - Tout afficher
On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes TERRANCE JOHN. HADLINGTON Aucun aperçu disponible - 2019 |
On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes Terrance John Hadlington Aucun aperçu disponible - 2017 |
