Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron CompoundsStable radicals - molecules with odd electrons which aresufficiently long lived to be studied or isolated usingconventional techniques - have enjoyed a long history and are ofcurrent interest for a broad array of fundamental and appliedreasons, for example to study and drive novel chemical reactions,in the development of rechargeable batteries or the study of freeradical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects ofOdd-Electron Compounds a team of international experts providea broad-based overview of stable radicals, from the fundamentalaspects of specific classes of stable neutral radicals to theirwide range of applications including synthesis, materials scienceand chemical biology. Topics covered include:
Stable Free Radicals: Fundamentals and Applied Aspects ofOdd-Electron Compounds is an essential guide to thisfascinating area of chemistry for researchers and students workingin organic and physical chemistry and materials science. |
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Table des matières
Persistent Radicals and van | |
Properties Synthesis | |
enhanced | |
Metal Coordinated Phenoxyl Radicals | |
NitroxideCatalyzed Alcohol Oxidations in Organic | |
Synthesis | |
of metals with nitroxides | |
Rechargeable Batteries Using Robust but Redox Active | |
A Modern Perspective Lawrence | |
biological systems | |
Functionalin vivo EPR Spectroscopy and Imaging Using | |
relevant small radicals | |
tert | |
Stable Radicals of the Heavy pBlock Elements | |
Application of Stable Radicals as Mediators in Living | |
systems | |
Index | |
Autres éditions - Tout afficher
Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds Robin Hicks Aucun aperçu disponible - 2010 |
Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds Robin Hicks Aucun aperçu disponible - 2010 |
Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds Robin Hicks Aucun aperçu disponible - 2010 |
Expressions et termes fréquents
acid alcohols alkoxyamine Angew antiferromagnetic Biol bond lengths carbon cation Chem chemical chemistry cm_1 complexes compounds coordination copper(ll Copyright corresponding crystal structure cyclic cyclic voltammetry Dalton Trans delocalized derivatives diamagnetic dichloromethane dimer diradical electron transfer electronic structure EPR spectrum Equation etal exhibits F. A. Neugebauer ferromagnetic Figure free radical heterospin hydrogen bonded hyperfine coupling interactions intramolecular kinetic Lett ligands lnorg Macromolecules magnetic properties materials metal ion moieties molecular molecular magnets molecules monomer neutral radical nitric oxide nitrogen atoms nitronyl nitroxide orbital oxygen paramagnetic persistent radical phenalenyl phenolate phenoxyl radicals Phys planar polymer potential probes protons PTM radicals radical anions radical polymerization reaction redox reduction Reprinted with permission resonance ring Scheme solid solution solvent species spectra spectroscopy spin density spin labeling stable radicals steric studies substituents synthesis temperature TEMPO Tetrahedron thiazyl radicals transition unpaired electron verdazyl X-ray
