Characterization and Design of Zeolite Catalysts: Solid Acidity, Shape Selectivity and Loading PropertiesSpringer Science & Business Media, 17 août 2010 - 186 pages Catalysis and catalyst is a key technology to solve the problems in energy and environment issues to sustain our human society. We believe that comprehensive understanding of the catalysis and catalyst provides us a chance to develop a new catalyst and contributes greatly to our society. However, the ?eld of heterogeneous catalyst is dif?cultto study andstill stays behindmoredeveloped?elds ofchemistry such as organic and physical chemistries. This is a dilemma to the chemists who study the catalysis and catalyst. While we can accomplish the progress in the - dustrial application, the scienti?c understandingis not complete yet. A gap between the useful application and incomplete scienti?c understanding, however, becomes smaller and smaller in recent years. Because zeolites are ?ne crystals, and the structure is clearly known, the study on the catalysis using the zeolites is easier than those encountered in other catalysts such as metals and metal oxides. Very fortunately, zeolites provide us the strong acidity with the ?ne distribution which enables various useful catalytic reactions. When some metals and cations are loaded in close to the acid sites, these loadede- ments show extraordinarycharacters, and many catalytic reactions proceed thereon. |
Table des matières
| 1 | |
Chapter 2 Solid Acidity of Zeolites | 9 |
Chapter 3 IRMSTPD Measurements of Acid Sites | 29 |
Chapter 4 DFT Calculation of the Solid Acidity | 61 |
Chapter 5 Catalytic Activity and Adsorption Property | 79 |
Chapter 6 CVD of Silica for the Shape Selective Reaction | 103 |
Chapter 7 Application of the CVD of Silica to the Shape Selective Reaction | 129 |
Chapter 8 Zeolite Loading Property for Active Sites and XAFS Measurements | 149 |
Chapter 9 Catalytic Reaction on the PalladiumLoaded Zeolites | 163 |
| 181 | |
Autres éditions - Tout afficher
Characterization and Design of Zeolite Catalysts: Solid Acidity, Shape ... Miki Niwa,Naonobu Katada,Kazu Okumura Aucun aperçu disponible - 2010 |
Characterization and Design of Zeolite Catalysts: Solid Acidity, Shape ... Miki Niwa,Naonobu Katada,Kazu Okumura Aucun aperçu disponible - 2012 |
Characterization and Design of Zeolite Catalysts: Solid Acidity, Shape ... Miki Niwa,Naonobu Katada,Kazu Okumura Aucun aperçu disponible - 2010 |
Expressions et termes fréquents
acid strength activation energy adsorbed adsorption alkane alkoxide ammonia desorption heat ammonia TPD atoms band position bromobenzene Brønsted acid sites Brønsted OH Catal catalyst catalytic activity cation Chabazite Chap Chem chemical chemical vapor deposition concentration coordination number cracking crystal CVD of silica deposited silica deposition of silica dispersed PdO EXAFS exchange degree experimental observation external surface extra-framework formation framework H-mordenite H-Y zeolite hydrocarbons IR-TPD isobutene Katada l-peak Lewis acid Lewis acid sites measured metal oxide metal Pd methanol method Microporous Mesoporous Mater molecule mordenite MS-TPD Murakami NH4+ Niwa number of acid o-xylene OH bands oxide parameters Pd clusters Pd loaded Pd-Pd peak periodic boundary Phys pore reduction sample shape selectivity shown in Fig shows Si.OEt silica silica deposited silica overlayer silicalite SiO2 sodalite solid acidity species spectra structure studied temperature Temperature/K tion toluene USY zeolite wavenumber XAFS zeolite acidity zeolite catalysts
