Monosaccharide Sugars: Chemical Synthesis by Chain Elongation, Degradation, and Epimerization

Couverture
Elsevier, 22 janv. 1998 - 508 pages
In a single volume, Monosaccharide Sugars critically summarizes the applied and potentially useful strategies for the synthesis and degradation of monosaccharides by chain-elongation, degradation, and epimerization. These methodologies permit the synthesis of rare or unnatural monosaccharides that are frequently employed as chiral building blocks in natural products synthesis, as well as for producing sugar derivatives labeled with radioactive isotopes. Representative and well-established experimental procedures are provided to illustrate the potential of the synthetic transformation.Degradation of carbohydrates also represents an invaluable tool for the structural elucidation of certain natural products, suchas glycosides, antibiotics, and polysaccharides. When describing the individual methods, unique supplementary collections of the prepared sugar derivatives are shown in tabular form. This compendium will eliminate tedious literature searches for those engaged in research and teaching on the chemistry and biochemistry of saccharides and other natural products, and also for those working on the medicinal and metabolic investigation of related substances of biological importance.
  • Illustrates the practical potential of well-established experimental procedures in synthetic transformations
  • Provides supplementary collections of prepared sugar derivatives in tabular form
  • Summarizes in a single volume the methods of obtaining carbohydrate-derived compounds
 

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Table des matières

Introduction
1
Chapter 1 Ascending Synthesis of Monosaccharides
3
Chapter 2 Descending Syntheses of Monosaccharides
375
Chapter 3 Preparation of Sugars with Isomerization
471
Notes Added in Proof
493
INDEX
499
Droits d'auteur

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Fréquemment cités

Page 30 - RG Ault, DK Baird, HC Carrington, WN Haworth, R. Herbert, EL Hirst, EGV Percival, F. Smith, and M. Stacey, J. Chem. Soc., p.
Page 28 - Namenreaktionen der organischen Chemie" Ein Beitrag zur Terminologie der organischen Chemie, Biochemie und theoretischen organischen Chemie.
Page 28 - HS Isbell, JV Karabinos, HL Frush, NB Holt, A. Schwebel, and TT Galkowski, J.

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