Modern Phosphonate Chemistry
A century after their discovery, phosphonates have become important compounds recognized both for their use as efficient reagents in organic synthesis and for their biological and industrial importance. This unique, up-to-date reference presents a concise summary of the state of the art in phosphonate chemistry, covering the role of phosphonates in traditional and modern organic syntheses. Its eight chapters explore the most important phosphonates and their applications in organic synthesis and includes 600 reaction schemes. As the first book to focus on this topic, Modern Phosphonate Chemistry will attract a wide readership in academia and industry, including organic and pharmaceutical chemists and biochemists.
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Chapter 2 The Silylphosphonates
Chapter 3 The Halogenophosphonates
Chapter 4 The Epoxyphosphonates
Chapter 5 The Formylphosphonates
Chapter 6 The Cyanophosphonates
Autres éditions - Tout afficher
1-alkynylphosphonates Abstr acetals acyl acylphosphonates Akad aldehydes alkyl allyl analogues anion Arbuzov aromatic Asymmetric synthesis Bull carbanions carbonyl carbonyl compounds carboxylic acid catalytic Chem Chim chlorides CO2Et Collignon cyanomethylphosphonate cyclization derivatives dialkyl electrophilic Elem enantioselective enol epoxide esters Et2O Et3N ethyl EtOH fluorination formation fosfomycin German Patent Appl give diethyl halides Heterocycles Horner–Wadsworth–Emmons reaction hydrogen hydrolysis i-Pr inhibitors intermediate intramolecular ketones Khim lithium low temperature Me3SiCl MeOH Michael addition Michaelis–Arbuzov reaction mixture n-BuLi nates Nauk SSSR nitriles novel nucleophilic Obshch olefination oxidation Perkin Trans phonates phosphonic acids phosphonoacetic phosphonylated phosphorus preparation presence Pudovik react reaction of diethyl reactivity reagents rearrangement reflux room temperature Savignac silyl SiMe3 stereoselective substituted Sulfur Silicon Relat Synth synthetic Tetrahedron Lett Total synthesis Transl treatment trialkyl phosphites triethyl phosphite trimethylsilyl U.S. Patent Appl USSR Engl vinyl vinylphosphonates yield Scheme