Microscopic Properties and Processes in Minerals

Couverture
Kate Wright, Charles Richard Arthur Catlow
Springer Science & Business Media, 31 oct. 1999 - 653 pages
One of the major developments in Earth Sciences in general, and mineralogy in particular, has been the growth of our understanding of the microscopic behaviour of the complex materials that make up the Earth. This has been made possible by advances in our ability to probe minerals at the atomic level, over a large range of pressure and temperature conditions. New experimental techniques include the use of scanning probe microscopies to investigate mineral surfaces, as well as the use of neutron scattering, nuclear spectroscopies and synchrotron radiation to investigate the bonding and structure of minerals. In addition, there have been major developments in computational methods so that it is now possible to calculate the electronic structure of many rock forming materials. The aim of this volume is to give a coherent survey of the latest developments in experimental and theoretical approaches to the study of microscopic propertie~ and processes in minerals. Chapters in the book cover a number of key themes in the mineral sciences such as the behaviour of minerals at extremes of pressure and temperature, ordering in complex silicates, mechanisms of water incorporation in mantle phases, the importance of reactions occurring at the mineral surface, and the ability of computational methods to provide useful, qualitative information on the bulk and surface properties of minerals. The background to several experimental techniques is covered in some detail with examples of relevance to the issues cited above.
 

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Table des matières

CRYSTAL STRUCTURES AT EXTREMES OF PRESSURE AND TEMPERATURE
1
EQUATIONS OF STATE
19
INTRODUCTION TO RAMAN SPECTROSCOPY AT EXTREME PRESSURE AND TEMPERATURE CONDITIONS
43
THERMODYNAMIC PROPERTIES OF MINERALS AT HIGH PRESSURES AND TEMPERATURES FROM VIBRATIONAL SPECTROSCOPIC D...
71
INTRODUCTION TO THE APPLICATION OF NEUTRON SPECTROSCOPY IN THE EARTH SCIENCES
93
SYNCHROTRON RADIATION AND SOLID STATE SCIENCE
145
IN SITU STRUCTURAL AND KINETIC POWDER DIFFRACTION STUDIES OF ALUMINOSILICATES
177
MINERAL SYNTHESIS BY FLUXGROWTH METHODS
189
ATOMIC STRUCTURE OF DISORDERED MATERIALS
371
PRINCIPLES OF SOLID STATE NMR SPECTROSCOPY AND APPLICATIONS TO DETERMINING LOCAL ORDER IN MINERALS
389
INTRODUCTION TO THE THEORY OF DISPLACIVE PHASE TRANSITIONS
427
ORDERING PHASE TRANSITIONS AND SOLID SOLUTIONS
451
PHASE TRANSITIONS AND EQUATIONS OF STATE
477
IR SPECTROSCOPY AND HYDROGEN BONDING IN MINERALS
493
WATER IN NOMINALLY ANHYDROUS MINERALS
509
CONTRIBUTION OF IR SPECTROSCOPY TO THE PROBLEM OF WATER IN THE EARTHS MANTLE
523

BONDING AND ELECTRONIC STRUCTURE OF MINERALS
201
CRYSTAL CHEMISTRY OF METAL SULFTDE MINERALS
265
INTRODUCTION TO THE THEORY OF LATTICE DYNAMICS
281
DISORDER AND DEFECTS IN SOLIDS
299
THE MODELLING OF BULK DIFFUSION IN SOLIDS
323
CLASSICAL COMPUTER SIMULATIONS
337
ABINITIO LCAO PERIODIC SIMULATIONS OF CRYSTAL PROPERTIES
351
SOLUBILITY AND DIFFUSION OF WATER IN SILICATE MINERALS
539
THE THEORY AND SIMULATION OF THE MELTING OF MINERALS
561
MOLECULAR DYNAMICS COMPUTER SIMULATIONS OF SILICATE GLASSES
577
PRINCIPLES APPLICATIONS AND CASE STUDIES
595
ATOMISTIC SIMULATION OF MINERAL SURFACES AND INTERFACES
629
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